Zirconium(IV) hydroxide

Zirconium(IV) hydroxide
Identifiers
CAS number 14475-63-9 Y
PubChem 84465
ChemSpider 76194 Y
Jmol-3D images Image 1
Properties
Molecular formula Zr(OH)4
Molar mass 159.253 g/mol
Appearance white filter cake
Density 3.25 g/cm3, solid
Melting point

550°C, decomposes

Solubility in water 0.02 g/100 mL (20 °C)
Hazards
EU classification not listed
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Except where noted otherwise, data are given for materials in their standard state (at 25 °C, 100 kPa)
Infobox references

Zirconium (IV) hydroxide is often called hydrous zirconia. It has an indeterminate chemical formula often described as ZrO2.nH2O. The formula ZrO2.2H2O being written as Zr(OH)4 gives rise to its description as a hydroxide. The compound is a toxic, amorphous white powder which is insoluble in water, but is soluble in dilute mineral acids.

Uses

It is primarily used as in intermediate for the manufacture of zirconium compounds. It is also used in pigments, glass and dyes. [1]

Preparation

Zirconium nitrate is prepared by reacting nitric acid with zirconium oxide:

ZrO2 + 4HNO3 → Zr(NO3)4 + 2H2O

The compound is crystallized as pentahydrate following evaporation to dryness.

References

  1. ^ "Zirconium Hydroxide". Product Identification. ChemicalLAND21.com. http://chemicalland21.com/industrialchem/inorganic/ZIRCONIUM%20HYDROXIDE.htm. Retrieved 2007-10-25.